Not really sure what you mean by an RF modulator. You might need to be a bit more specific.
A/V means audio/video. So basically any connector that outputs audio and video is an A/V jack. Even RF. Some people call composite (yellow,white,red) A/V - for some reason. Kind of like how people say that their NES top loader is A/V modded. What they mean is that it has Composite audio and video. Not sure when or why they ever got mixed up.